Please use this identifier to cite or link to this item:
http://hdl.handle.net/11375/20217
Title: | Solution-Stability Relationships of Metal 8-Hydroxyquinolinates |
Authors: | Steger, Henry Frank |
Advisor: | Corsini, A. |
Department: | Chemistry |
Keywords: | solution, stability, metals, relationships, hydroxyquinolinates, ions, solvent, composition, bond |
Publication Date: | Aug-1969 |
Abstract: | <p> The solution stability of chelates formed between several metal-ions and 5-substituted-8-hydroxyquinolines has been determined. The dependence of solution stability on (a) the solvent composition, and (b) the basicity of the ligand donor sites has been examined.</p> <p> It was found that the effect of solvent composition on metal chelate stability is essentially independent of the metal-ion. A mathematical description of the relationship between metal-chelate stability and ligand basicity has been derived and gives excellent agreement with the experimental data. The relative contributions of the N-M and the O-M bond to chelate stability are evaluated and shown to vary slightly with the metal-ion. Also, the character of the bonding in the metal chelates is implied.</p> |
URI: | http://hdl.handle.net/11375/20217 |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Steger_Henry_F._1969Aug_Ph.D..pdf | 3.86 MB | Adobe PDF | View/Open |
Items in MacSphere are protected by copyright, with all rights reserved, unless otherwise indicated.