Solution-Stability Relationships of Metal 8-Hydroxyquinolinates
| dc.contributor.advisor | Corsini, A. | |
| dc.contributor.author | Steger, Henry Frank | |
| dc.contributor.department | Chemistry | en_US |
| dc.date.accessioned | 2016-08-25T18:06:01Z | |
| dc.date.available | 2016-08-25T18:06:01Z | |
| dc.date.issued | 1969-08 | |
| dc.description.abstract | <p> The solution stability of chelates formed between several metal-ions and 5-substituted-8-hydroxyquinolines has been determined. The dependence of solution stability on (a) the solvent composition, and (b) the basicity of the ligand donor sites has been examined.</p> <p> It was found that the effect of solvent composition on metal chelate stability is essentially independent of the metal-ion. A mathematical description of the relationship between metal-chelate stability and ligand basicity has been derived and gives excellent agreement with the experimental data. The relative contributions of the N-M and the O-M bond to chelate stability are evaluated and shown to vary slightly with the metal-ion. Also, the character of the bonding in the metal chelates is implied.</p> | en_US |
| dc.description.degree | Doctor of Philosophy (PhD) | en_US |
| dc.description.degreetype | Thesis | en_US |
| dc.identifier.uri | http://hdl.handle.net/11375/20217 | |
| dc.language.iso | en_US | en_US |
| dc.subject | solution, stability, metals, relationships, hydroxyquinolinates, ions, solvent, composition, bond | en_US |
| dc.title | Solution-Stability Relationships of Metal 8-Hydroxyquinolinates | en_US |
| dc.type | Thesis | en_US |