Thermal decomposition of a Δ³-oxadiazoline
| dc.contributor.advisor | Warkentin, J. | en_US |
| dc.contributor.author | Bekhazi, Michel | en_US |
| dc.contributor.department | Chemistry | en_US |
| dc.date.accessioned | 2014-06-18T16:40:24Z | |
| dc.date.available | 2014-06-18T16:40:24Z | |
| dc.date.created | 2009-07-11 | en_US |
| dc.date.issued | 1979-11 | en_US |
| dc.description.abstract | <p>2-Methoxy-2,5,5-trimethyl-Δ³-1,3,4-oxadiazoline was synthesized and decomposed neat, in the presence of carbon tetrachloride and in the presence of deuterated benzene. Because of the production of propene when C₆D₆ was the solvent and chlorinated products when CCl₄ was the solvent, a carbene mechanism is proposed. The evidence in support of this mechanism is strengthened by the trapping of the carbene intermediates with 1,1-diphenylethylene and the reaction of independently generated dimethylcarbene with CCl₄.</p> | en_US |
| dc.description.degree | Master of Science (MS) | en_US |
| dc.identifier.other | opendissertations/302 | en_US |
| dc.identifier.other | 1312 | en_US |
| dc.identifier.other | 894594 | en_US |
| dc.identifier.uri | http://hdl.handle.net/11375/7764 | |
| dc.subject | Chemistry | en_US |
| dc.subject | Chemistry | en_US |
| dc.title | Thermal decomposition of a Δ³-oxadiazoline | en_US |
| dc.type | thesis | en_US |
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