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Thermal decomposition of a Δ³-oxadiazoline

dc.contributor.advisorWarkentin, J.en_US
dc.contributor.authorBekhazi, Michelen_US
dc.contributor.departmentChemistryen_US
dc.date.accessioned2014-06-18T16:40:24Z
dc.date.available2014-06-18T16:40:24Z
dc.date.created2009-07-11en_US
dc.date.issued1979-11en_US
dc.description.abstract<p>2-Methoxy-2,5,5-trimethyl-Δ³-1,3,4-oxadiazoline was synthesized and decomposed neat, in the presence of carbon tetrachloride and in the presence of deuterated benzene. Because of the production of propene when C₆D₆ was the solvent and chlorinated products when CCl₄ was the solvent, a carbene mechanism is proposed. The evidence in support of this mechanism is strengthened by the trapping of the carbene intermediates with 1,1-diphenylethylene and the reaction of independently generated dimethylcarbene with CCl₄.</p>en_US
dc.description.degreeMaster of Science (MS)en_US
dc.identifier.otheropendissertations/302en_US
dc.identifier.other1312en_US
dc.identifier.other894594en_US
dc.identifier.urihttp://hdl.handle.net/11375/7764
dc.subjectChemistryen_US
dc.subjectChemistryen_US
dc.titleThermal decomposition of a Δ³-oxadiazolineen_US
dc.typethesisen_US

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