The Electronic Spectra of CSClF and CSCl₂
| dc.contributor.advisor | Moule, D. C. | en_US |
| dc.contributor.author | Subramaniam, Ramaswamy Chandrasekarapuram | en_US |
| dc.contributor.department | Chemistry | en_US |
| dc.date.accessioned | 2014-06-18T16:43:06Z | |
| dc.date.available | 2014-06-18T16:43:06Z | |
| dc.date.created | 2010-12-20 | en_US |
| dc.date.issued | 1972-10 | en_US |
| dc.description.abstract | <p>Three electronic absorption systems of thiocarbonylchlorofluoride have been observed in the visible and ultraviolet regions and have been assigned to the electronic transitions a⁻³A" ← X⁻¹A', A⁻¹A" ← X⁻¹A' and B⁻¹A' ← X⁻¹lA'. A vibrational analysis of these system has been carried out. The geometry of thiocarbonylchlorofluoride in the upper states a⁻³A", A⁻¹A" and B¹A' has been found to be nonplanar, while he molecule is planar in the ground state. A vibrational analysis of the visible absorption system (a⁻³A₂ ← X⁻¹A) of thiocarbonyldtchloride has been carried out and the excited state geometry of the molecule is found to be nonplanar with an out-of-plane angle of about 33°.</p> | en_US |
| dc.description.degree | Doctor of Philosophy (PhD) | en_US |
| dc.identifier.other | opendissertations/3704 | en_US |
| dc.identifier.other | 4721 | en_US |
| dc.identifier.other | 1702839 | en_US |
| dc.identifier.uri | http://hdl.handle.net/11375/8503 | |
| dc.subject | Chemistry | en_US |
| dc.subject | Chemistry | en_US |
| dc.title | The Electronic Spectra of CSClF and CSCl₂ | en_US |
| dc.type | thesis | en_US |
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