The Electronic Absorption Spectrum of Thioformaldehyde (CH₂S)
| dc.contributor.advisor | King, G. W. | |
| dc.contributor.author | Judge, Richard Henry | |
| dc.contributor.department | Chemistry | en_US |
| dc.date.accessioned | 2015-10-30T13:20:25Z | |
| dc.date.available | 2015-10-30T13:20:25Z | |
| dc.date.issued | 1977-05 | |
| dc.description.abstract | The ¹A₂ ← ¹A₁ (π* ← n) electronic absorption spectrum of thioformaldehyde vapour has been investigated. The six excited state fundamental frequencies for both CH₂S and CD₂S are determined from the vibrational analysis. The three rotation constants and three symmetric top distortion constants for the 0⁰₀, 4¹₀ and 3¹₀4³₀ bands of CH₂S and the 0⁰₀, 4¹₀ and 5¹₀ bands of CD2S are determined from a least squares rotational analysis of these bands. The rotational constants of the 0⁰₀ and 4¹₀ bands of CH₂S and CD₂S are used to determine the structure of the molecule in the excited state. | en_US |
| dc.description.degree | Doctor of Philosophy (PhD) | en_US |
| dc.description.degreetype | Thesis | en_US |
| dc.identifier.uri | http://hdl.handle.net/11375/18491 | |
| dc.language.iso | en | en_US |
| dc.subject | chemistry | en_US |
| dc.subject | electronic absorption spectrum | en_US |
| dc.subject | thioformaldehyde | en_US |
| dc.title | The Electronic Absorption Spectrum of Thioformaldehyde (CH₂S) | en_US |