Photochemistry of Triphenylmethylcyclopentadiene
| dc.contributor.advisor | Warkentin, J. | en_US |
| dc.contributor.author | Weigl, Stefan | en_US |
| dc.contributor.department | Chemistry | en_US |
| dc.date.accessioned | 2014-06-18T16:46:08Z | |
| dc.date.available | 2014-06-18T16:46:08Z | |
| dc.date.created | 2009-06-24 | en_US |
| dc.date.issued | 1975-09 | en_US |
| dc.description.abstract | <p>The products and mechanism of the photolytic rearrangement of the equilibrium mixture of triphenylmethylcyclopentadienes have been studied. Direct irradiation of the equilibrium mixture of triphenylmethylcyclopentadienes yields 5,6,6-triphenylibicyclo{3.1.0} hex-2-ene. Photolysis with a triplet sensitizer yields dimeric products in addition to 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene. Thermolytic isomerization of 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene is reported. The predominant isomer in the equilibrium mixture of triphenylmethylcyclopentadiene has been established as 2-triphenylmethylcyclopentadiene.</p> | en_US |
| dc.description.degree | Master of Science (MS) | en_US |
| dc.identifier.other | opendissertations/435 | en_US |
| dc.identifier.other | 1179 | en_US |
| dc.identifier.other | 880470 | en_US |
| dc.identifier.uri | http://hdl.handle.net/11375/9206 | |
| dc.subject | Chemistry | en_US |
| dc.subject | Chemistry | en_US |
| dc.title | Photochemistry of Triphenylmethylcyclopentadiene | en_US |
| dc.type | thesis | en_US |
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