X-Ray Crystal Structure Investigation of [Re(C5H5N)4 O2]Cl.2H20
| dc.contributor.advisor | Lock, C. J. L. | |
| dc.contributor.author | Krishnamachari, Narasimhan | |
| dc.contributor.department | Chemistry | en_US |
| dc.date.accessioned | 2015-09-24T15:40:58Z | |
| dc.date.available | 2015-09-24T15:40:58Z | |
| dc.date.issued | 1968-05 | |
| dc.description.abstract | <p> The crystal structure of dioxotetrapyridine-rhenium(V) chloride dihydrate has been determined by single crystal x-ray diffraction methods. The structure has been found to belong to the trans-dioxo- group of compounds. The Re=O bond in the structure has been shown to have a bond-order of about 2, with the average Re=O bond length of 1.76(J) A. The probable structures of the monohydrate and anhydrous dioxotetrapyridine-rhenium(V) chloride have been discussed on the basis of the observed pseudo-symmetric structure for the dihydrate with a non-centrosymmetric space group. The nature and strength of the hydrogen bonds in the structure have also been discussed.</p> | en_US |
| dc.description.degree | Master of Science (MSc) | en_US |
| dc.description.degreetype | Thesis | en_US |
| dc.identifier.uri | http://hdl.handle.net/11375/18106 | |
| dc.language.iso | en_US | en_US |
| dc.subject | crystal, structure, x-ray, diffraction, bonds | en_US |
| dc.title | X-Ray Crystal Structure Investigation of [Re(C5H5N)4 O2]Cl.2H20 | en_US |
| dc.type | Thesis | en_US |