Photochemistry of Triphenylmethylcyclopentadiene
| dc.contributor.advisor | Warkentin, J. | |
| dc.contributor.author | Weigl, Stefan | |
| dc.contributor.department | Chemistry | en_US |
| dc.date.accessioned | 2016-10-06T16:57:44Z | |
| dc.date.available | 2016-10-06T16:57:44Z | |
| dc.date.issued | 1975-09 | |
| dc.description.abstract | <p> The products and mechanism of the photolytic rearrangement of the equilibrium mixture of triphenylmethylcyclopentadienes have been studied. Direct irradiation of the equilibrium mixture of triphenylmethylcyclopentadienes yields 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene. Photolysis with a triplet sensitizer yields dimeric products in addition to 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene. Thermolytic isomerization of 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene is reported. The predominant isomer in the equilibrium mixture of triphenylmethylcyclopentadiene has been established as 2-triphenylmethylcyclopentadiene.</p> | en_US |
| dc.description.degree | Master of Science (MSc) | en_US |
| dc.description.degreetype | Thesis | en_US |
| dc.identifier.uri | http://hdl.handle.net/11375/20673 | |
| dc.language.iso | en_US | en_US |
| dc.subject | photochemistry, direct irradiation, thermolytic isomerization | en_US |
| dc.title | Photochemistry of Triphenylmethylcyclopentadiene | en_US |
| dc.type | Thesis | en_US |