Please use this identifier to cite or link to this item:
http://hdl.handle.net/11375/8495
Title: | Model Potentials and Molecular Rydberg Series |
Authors: | Greening, Richard Frank |
Advisor: | King, G.W. |
Department: | Chemistry |
Keywords: | Chemistry;Chemistry |
Publication Date: | Aug-1973 |
Abstract: | <p>M0del potential calculations have been carried out on the πg → nsσg, npσu and npπu Rydberg series of CO₂, CS₂ and Cse₂. The molecular potential was represented by a super-position of atomic model potentials which were calibrated to atomic data. The Rydberg M.O. was expanded about the molecular mid-point in many members of a linear combination of hydrogen functions and of a Rydberg series were obtained in a single calculation on a computer. The results of the calculations were used to check previous assignments of Rydberg series in CO₂ and CS₂. The previously unreported vacuum u-v spectrum of CSe₂ was observed in the region from 1200-2000 Å, and analysed using the model calculations.</p> |
URI: | http://hdl.handle.net/11375/8495 |
Identifier: | opendissertations/3698 4715 1702474 |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
File | Size | Format | |
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fulltext.pdf | 4.1 MB | Adobe PDF | View/Open |
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