Skip navigation
  • Home
  • Browse
    • Communities
      & Collections
    • Browse Items by:
    • Publication Date
    • Author
    • Title
    • Subject
    • Department
  • Sign on to:
    • My MacSphere
    • Receive email
      updates
    • Edit Profile


McMaster University Home Page
  1. MacSphere
  2. Open Access Dissertations and Theses Community
  3. Digitized Open Access Dissertations and Theses
Please use this identifier to cite or link to this item: http://hdl.handle.net/11375/32087
Title: EQUILIBRIUM CONSTANTS FOR SULPHUR ISOTOPE EXCHANGE
Authors: Cragg, Charles
Advisor: Thode, Dr. H.G
Department: Chemistry
Publication Date: Oct-1961
Abstract: The equilibrium constant for the exchange of the sulphur isotopes between hydrogen sulphide and sulphur dioxide was measured at temperatures ranging from 700 K to 1500 K. For comparison with these neaBurementa, values of the equilibrium constant wore calculated, the calculations being based on ho statistical mechanical theory of isotope effects and on spectroscopic data taken from the literature. Although the experimental results wore qualitatively consistent with theoretical predictions, there was a discrepancy between the experimental and calculated values. This discrepancy woo tentatively ascribed to uncertainty in the vibrational isotope shifts of hydrogen sulphide
URI: http://hdl.handle.net/11375/32087
Appears in Collections:Digitized Open Access Dissertations and Theses

Files in This Item:
File Description SizeFormat 
cragg_charles_Oct_1961..pdf
Open Access
4.06 MBAdobe PDFView/Open
Show full item record Statistics


Items in MacSphere are protected by copyright, with all rights reserved, unless otherwise indicated.

Sherman Centre for Digital Scholarship     McMaster University Libraries
©2022 McMaster University, 1280 Main Street West, Hamilton, Ontario L8S 4L8 | 905-525-9140 | Contact Us | Terms of Use & Privacy Policy | Feedback

Report Accessibility Issue