Please use this identifier to cite or link to this item:
http://hdl.handle.net/11375/20366
Title: | Uranium(VI) and Scandium(III) Complexes of a-Hydroxyquinoline and Derivatives |
Authors: | Thompson, Michael |
Advisor: | Corsini, A. |
Department: | Chemistry |
Keywords: | uranium;scandium;derivatives;zwitterion |
Publication Date: | Sep-1970 |
Abstract: | <p> New uranium(VI) complexes of a-hydroxyquinoline ligands of formulae U02(R-Q)2 R-QH have been prepared. In these compounds, the additional liquid is likely bonded as a zwitterion. Appropriate substitution in the 2- and 7-positions lead to interesting steric effects. Some uranium(VI) complexes reported in the literature have been re-examined and found to be incorrectly formulated. </p> <p> The scandium(III) complex of a-hydroxyquinoline obtained from aqueous solution was. found to be Sc(C9H6N0) 3 •H20 and not Sc(CgH&N0) 3 •C 9H7NO as previously reported. In the absence of water, Sc (CgH&NO) 3 •C 9H7NO 'Was obtained. New scandium(III) complexes of formulae Sc(R-Q) 3 •R-QH and Sc(R-Q) 3 •H20 have been prepared. </p> |
URI: | http://hdl.handle.net/11375/20366 |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
File | Description | Size | Format | |
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Thompson_Micheal_1970Sept_Phd.pdf | 6.38 MB | Adobe PDF | View/Open |
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