The Vapour-Phase Reaction of 2-Alkyltetrahydropyrans with Anilik over Alumina
| dc.contributor.advisor | Bourne, A.N. | |
| dc.contributor.author | Richards, Harry | |
| dc.contributor.department | Chemistry | en_US |
| dc.date.accessioned | 2020-08-28T16:56:44Z | |
| dc.date.available | 2020-08-28T16:56:44Z | |
| dc.date.issued | 1952-10 | |
| dc.description.abstract | The vapour-phase reaction of 2-methy-tetrhydropyran and 2-ethyltetralydropyran with aniline over an activated alumina catalyst has been studied. The product, in each case, consisted of a mature of an N-aryl-piperidine, an N-arylpyrrolidine formed by ring contraction, and two N-alkelnylanilines formed by ring opening. The structures of the nitrogen heterocyclic compounds were established by independent syntheses involving the reaction of the appropriate dibromoalkane with aniline. The N-alkenylanilines were characterised by hydrogenation to known N-alkylanilines and by identification of the osonolysis products. | en_US |
| dc.description.degree | Master of Science (MSc) | en_US |
| dc.description.degreetype | Thesis | en_US |
| dc.identifier.uri | http://hdl.handle.net/11375/25749 | |
| dc.language.iso | en | en_US |
| dc.subject | vapour-phase reaction | en_US |
| dc.subject | 2-alkyltetrahydropyrans | en_US |
| dc.subject | aniline | en_US |
| dc.subject | alumina | en_US |
| dc.title | The Vapour-Phase Reaction of 2-Alkyltetrahydropyrans with Anilik over Alumina | en_US |
| dc.type | Thesis | en_US |