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http://hdl.handle.net/11375/9910
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DC Field | Value | Language |
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dc.contributor.advisor | Worstiuk, Nick H. | en_US |
dc.contributor.author | Vancas, Frank Ivan | en_US |
dc.date.accessioned | 2014-06-18T16:48:47Z | - |
dc.date.available | 2014-06-18T16:48:47Z | - |
dc.date.created | 2009-06-18 | en_US |
dc.date.issued | 1975-10 | en_US |
dc.identifier.other | opendissertations/499 | en_US |
dc.identifier.other | 1115 | en_US |
dc.identifier.other | 875819 | en_US |
dc.identifier.uri | http://hdl.handle.net/11375/9910 | - |
dc.description.abstract | <p>The mechanism of 1,3-elimination in the bicyclo(2,2,1)heptyl system was studied using mass spectrometry and gas chromatography. The ionic chlorination, bromination, and iodo monochlorination of 2,3-d₂-norbornene, exo, exo-5, 6-d₂-norbornene, and endo, endo-5, 6-d₂-norbornene were performed to obtain deuterium loss data. In the chlorination of norbornene, most of the tricyclic product arises from the cyclic norbornyl chloronium ion and/or classical exo-S-chloronorbornyl cation (classical ion interpretation), or from the cyclic norbornyl chloronium ion (non-classical ion interpretation). In the bromination of norbornene, most of the tricyclic product arises from the classical syn-7-bromonorbornyl cation and/or anti-7-bromonorbornyl cation (classical ion interpretation), or from the first formed non-classical 3-bromonorbornyl cation (non-classical ion interpretation). In the iodo monochlorination of norbornene, most of the tricyclic product arises from the classical syn-7-iodo-norbornyl cation (classical ion interpretation), or from the first formed non-classical 3-iodonorbornyl cation (non-classical ion interpretation. Three of the products from the reaction of norbornene with iodo monochloride were isolated and identified to be: 3-iodonortricyclene, exo-2-iodo-endo-3-chloronorbornane, and syn-7-iodo-exo-2-chloronorbornane.</p> | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Chemistry | en_US |
dc.title | On the Mechanism of Ionic 1,3-Elimination in the Formation of Halonortricyclones | en_US |
dc.type | thesis | en_US |
dc.contributor.department | Chemistry | en_US |
dc.description.degree | Master of Science (MS) | en_US |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
File | Size | Format | |
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fulltext.pdf | 3.51 MB | Adobe PDF | View/Open |
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