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http://hdl.handle.net/11375/9206| Title: | Photochemistry of Triphenylmethylcyclopentadiene |
| Authors: | Weigl, Stefan |
| Advisor: | Warkentin, J. |
| Department: | Chemistry |
| Keywords: | Chemistry;Chemistry |
| Publication Date: | Sep-1975 |
| Abstract: | <p>The products and mechanism of the photolytic rearrangement of the equilibrium mixture of triphenylmethylcyclopentadienes have been studied. Direct irradiation of the equilibrium mixture of triphenylmethylcyclopentadienes yields 5,6,6-triphenylibicyclo{3.1.0} hex-2-ene. Photolysis with a triplet sensitizer yields dimeric products in addition to 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene. Thermolytic isomerization of 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene is reported. The predominant isomer in the equilibrium mixture of triphenylmethylcyclopentadiene has been established as 2-triphenylmethylcyclopentadiene.</p> |
| URI: | http://hdl.handle.net/11375/9206 |
| Identifier: | opendissertations/435 1179 880470 |
| Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
| File | Size | Format | |
|---|---|---|---|
| fulltext.pdf | 1.75 MB | Adobe PDF | View/Open |
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