The Preparation and Chemistry of Oxadiazolinones and Oxadiazolines

Please use this identifier to cite or link to this item: http://hdl.handle.net/11375/8539

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DC Field	Value	Language
dc.contributor.advisor	Warkentin, J.	en_US
dc.contributor.author	Knittel, Peter	en_US
dc.date.accessioned	2014-06-18T16:43:12Z	-
dc.date.available	2014-06-18T16:43:12Z	-
dc.date.created	2010-12-22	en_US
dc.date.issued	1975-06	en_US
dc.identifier.other	opendissertations/3737	en_US
dc.identifier.other	4755	en_US
dc.identifier.other	1705403	en_US
dc.identifier.uri	http://hdl.handle.net/11375/8539	-
dc.description.abstract	<p>The objectives of this work were fourfold. Firstly, the oxidation of semicarbazones with lead tetraacetate was examined from the point of view of products and of mechanism, as related to the mechanisms of other lead tetraacetate oxidations of carbonyl derivatives. Secondly, the chemistry of the acetone semicarbazone oxidation product, 5,5-dimethyl-Δ³-1,3,4-oxadiazolin-2-one was investigated. Thirdly, the chemistry of the methyl Iithium addition product of 5,5-dimethyl-Δ³-1,3,4-oxadiazolin-2-one, 2-hydroxy-2,5,5-trimethyl-Δ³-1,3,4-oxadiazoline, was studied mainly from the aspect of its novel radical chain thermal decomposition. Fourthly, a general principle regarding radical pathways was put forward.</p>	en_US
dc.subject	Chemistry	en_US
dc.subject	Chemistry	en_US
dc.title	The Preparation and Chemistry of Oxadiazolinones and Oxadiazolines	en_US
dc.type	thesis	en_US
dc.contributor.department	Chemistry	en_US
dc.description.degree	Doctor of Philosophy (PhD)	en_US
Appears in Collections:	Open Access Dissertations and Theses

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