The Electronic Spectra of CSClF and CSCl₂

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DC Field	Value	Language
dc.contributor.advisor	Moule, D. C.	en_US
dc.contributor.author	Subramaniam, Ramaswamy Chandrasekarapuram	en_US
dc.date.accessioned	2014-06-18T16:43:06Z	-
dc.date.available	2014-06-18T16:43:06Z	-
dc.date.created	2010-12-20	en_US
dc.date.issued	1972-10	en_US
dc.identifier.other	opendissertations/3704	en_US
dc.identifier.other	4721	en_US
dc.identifier.other	1702839	en_US
dc.identifier.uri	http://hdl.handle.net/11375/8503	-
dc.description.abstract	<p>Three electronic absorption systems of thiocarbonylchlorofluoride have been observed in the visible and ultraviolet regions and have been assigned to the electronic transitions a⁻³A" ← X⁻¹A', A⁻¹A" ← X⁻¹A' and B⁻¹A' ← X⁻¹lA'. A vibrational analysis of these system has been carried out. The geometry of thiocarbonylchlorofluoride in the upper states a⁻³A", A⁻¹A" and B¹A' has been found to be nonplanar, while he molecule is planar in the ground state. A vibrational analysis of the visible absorption system (a⁻³A₂ ← X⁻¹A) of thiocarbonyldtchloride has been carried out and the excited state geometry of the molecule is found to be nonplanar with an out-of-plane angle of about 33°.</p>	en_US
dc.subject	Chemistry	en_US
dc.subject	Chemistry	en_US
dc.title	The Electronic Spectra of CSClF and CSCl₂	en_US
dc.type	thesis	en_US
dc.contributor.department	Chemistry	en_US
dc.description.degree	Doctor of Philosophy (PhD)	en_US
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