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http://hdl.handle.net/11375/8503| Title: | The Electronic Spectra of CSClF and CSCl₂ |
| Authors: | Subramaniam, Ramaswamy Chandrasekarapuram |
| Advisor: | Moule, D. C. |
| Department: | Chemistry |
| Keywords: | Chemistry;Chemistry |
| Publication Date: | Oct-1972 |
| Abstract: | <p>Three electronic absorption systems of thiocarbonylchlorofluoride have been observed in the visible and ultraviolet regions and have been assigned to the electronic transitions a⁻³A" ← X⁻¹A', A⁻¹A" ← X⁻¹A' and B⁻¹A' ← X⁻¹lA'. A vibrational analysis of these system has been carried out. The geometry of thiocarbonylchlorofluoride in the upper states a⁻³A", A⁻¹A" and B¹A' has been found to be nonplanar, while he molecule is planar in the ground state. A vibrational analysis of the visible absorption system (a⁻³A₂ ← X⁻¹A) of thiocarbonyldtchloride has been carried out and the excited state geometry of the molecule is found to be nonplanar with an out-of-plane angle of about 33°.</p> |
| URI: | http://hdl.handle.net/11375/8503 |
| Identifier: | opendissertations/3704 4721 1702839 |
| Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
| File | Size | Format | |
|---|---|---|---|
| fulltext.pdf | 2.51 MB | Adobe PDF | View/Open |
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