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http://hdl.handle.net/11375/7764
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DC Field | Value | Language |
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dc.contributor.advisor | Warkentin, J. | en_US |
dc.contributor.author | Bekhazi, Michel | en_US |
dc.date.accessioned | 2014-06-18T16:40:24Z | - |
dc.date.available | 2014-06-18T16:40:24Z | - |
dc.date.created | 2009-07-11 | en_US |
dc.date.issued | 1979-11 | en_US |
dc.identifier.other | opendissertations/302 | en_US |
dc.identifier.other | 1312 | en_US |
dc.identifier.other | 894594 | en_US |
dc.identifier.uri | http://hdl.handle.net/11375/7764 | - |
dc.description.abstract | <p>2-Methoxy-2,5,5-trimethyl-Δ³-1,3,4-oxadiazoline was synthesized and decomposed neat, in the presence of carbon tetrachloride and in the presence of deuterated benzene. Because of the production of propene when C₆D₆ was the solvent and chlorinated products when CCl₄ was the solvent, a carbene mechanism is proposed. The evidence in support of this mechanism is strengthened by the trapping of the carbene intermediates with 1,1-diphenylethylene and the reaction of independently generated dimethylcarbene with CCl₄.</p> | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Chemistry | en_US |
dc.title | Thermal decomposition of a Δ³-oxadiazoline | en_US |
dc.type | thesis | en_US |
dc.contributor.department | Chemistry | en_US |
dc.description.degree | Master of Science (MS) | en_US |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
File | Size | Format | |
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fulltext.pdf | 871.83 kB | Adobe PDF | View/Open |
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