Thermal decomposition of a Δ³-oxadiazoline

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DC Field	Value	Language
dc.contributor.advisor	Warkentin, J.	en_US
dc.contributor.author	Bekhazi, Michel	en_US
dc.date.accessioned	2014-06-18T16:40:24Z	-
dc.date.available	2014-06-18T16:40:24Z	-
dc.date.created	2009-07-11	en_US
dc.date.issued	1979-11	en_US
dc.identifier.other	opendissertations/302	en_US
dc.identifier.other	1312	en_US
dc.identifier.other	894594	en_US
dc.identifier.uri	http://hdl.handle.net/11375/7764	-
dc.description.abstract	<p>2-Methoxy-2,5,5-trimethyl-Δ³-1,3,4-oxadiazoline was synthesized and decomposed neat, in the presence of carbon tetrachloride and in the presence of deuterated benzene. Because of the production of propene when C₆D₆ was the solvent and chlorinated products when CCl₄ was the solvent, a carbene mechanism is proposed. The evidence in support of this mechanism is strengthened by the trapping of the carbene intermediates with 1,1-diphenylethylene and the reaction of independently generated dimethylcarbene with CCl₄.</p>	en_US
dc.subject	Chemistry	en_US
dc.subject	Chemistry	en_US
dc.title	Thermal decomposition of a Δ³-oxadiazoline	en_US
dc.type	thesis	en_US
dc.contributor.department	Chemistry	en_US
dc.description.degree	Master of Science (MS)	en_US
Appears in Collections:	Open Access Dissertations and Theses

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