Please use this identifier to cite or link to this item:
http://hdl.handle.net/11375/7764
Title: | Thermal decomposition of a Δ³-oxadiazoline |
Authors: | Bekhazi, Michel |
Advisor: | Warkentin, J. |
Department: | Chemistry |
Keywords: | Chemistry;Chemistry |
Publication Date: | Nov-1979 |
Abstract: | <p>2-Methoxy-2,5,5-trimethyl-Δ³-1,3,4-oxadiazoline was synthesized and decomposed neat, in the presence of carbon tetrachloride and in the presence of deuterated benzene. Because of the production of propene when C₆D₆ was the solvent and chlorinated products when CCl₄ was the solvent, a carbene mechanism is proposed. The evidence in support of this mechanism is strengthened by the trapping of the carbene intermediates with 1,1-diphenylethylene and the reaction of independently generated dimethylcarbene with CCl₄.</p> |
URI: | http://hdl.handle.net/11375/7764 |
Identifier: | opendissertations/302 1312 894594 |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
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fulltext.pdf | 871.83 kB | Adobe PDF | View/Open |
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