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http://hdl.handle.net/11375/6240
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DC Field | Value | Language |
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dc.contributor.advisor | Gillespie, R.J. | en_US |
dc.contributor.author | Chartier, Robert Duane | en_US |
dc.date.accessioned | 2014-06-18T16:34:35Z | - |
dc.date.available | 2014-06-18T16:34:35Z | - |
dc.date.created | 2010-04-03 | en_US |
dc.date.issued | 1982-04 | en_US |
dc.identifier.other | opendissertations/1565 | en_US |
dc.identifier.other | 2128 | en_US |
dc.identifier.other | 1260553 | en_US |
dc.identifier.uri | http://hdl.handle.net/11375/6240 | - |
dc.description.abstract | <p>Novel synthetic pathways for the production of infinite mercury chain materials (Hg₃₋δMF₆) were investigated and some of the physical properties of the materials were studied. The solution chemistry of the homopolyatomic cation system (Hg₂²⁺, Hg₃²⁺, Hg₄²⁺) from which either Hg₃₋δAsF₆ or Hg₃₋δSbF₆ are formed was probed using ¹⁹⁹Hg NMR (Nuclear Magnetic Resonance).</p> <p>Both O₂⁺ and NO+ salts of the ASF¯₆ or SbF¯₆ ions oxidized metallic mercury to produce the known materials Hg₃₋δMF₆.</p> <p>Differential Thermal Analysis (DTA) was used to study both low and high temperature phase transitions in the conducting materials. A phase transition at approximately 235 K has been associated with the reversible anisotropic extrusion of mercury from the crystals.</p> <p>The thermal and hydrolytic decomposition pathways for Hg₃₋δAsF₆ were characterized and the absolute reflectance was also measured.</p> | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Chemistry | en_US |
dc.title | The Synthesis and Physical Properties of Infinite Mercury Chain Conducting Materials | en_US |
dc.type | thesis | en_US |
dc.contributor.department | Chemistry | en_US |
dc.description.degree | Doctor of Philosophy (PhD) | en_US |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
File | Size | Format | |
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fulltext.pdf | 3.53 MB | Adobe PDF | View/Open |
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