Mechanical Properties of Nickel Zirconia Interpenetrating Phase Composites

Abstract

This thesis describes the processing and testing of homogeneous nickel and fully yttria stabilized cubic zirconia interpenetrating phase composites. This work was part of a research program investigating step graded Functionally Gradient Materials. This work was focused on understanding the deformation behaviour of the interpenetrating composites near the percolation threshold of the ceramic phase. The composite grades selected for this study included the pure materials, nickel and zirconia, as well as composites with volume fractions of zirconia of 5%, 10%, 15%, 20% and 25%. These compositions were selected to provide data near the zirconia percolation threshold. Processing of the composites involved tape casting, lamination, organic removal, reduction, and hot pressing. All composites except the 5% volume fraction achieved densities greater than 98% of theoretical. Tensile testing was performed on composite grades up to and including the 20% zirconia material, and flexural testing was carried out on the 25% material and pure zirconia. The maximum tensile strength of 530 MPa was obtained in the 10% material resulting from load transfer to the zirconia phase. Ductility decreased as the volume fraction of zirconia increased, with no macroscopic plasticity above 15% volume fraction zirconia. Hardness tests and compression tests were carried out on all composite grades and the yield stress was determined.The compressive yield stress was found to be related to the hardness by the equation: H=6σy This relationship is a result of the constraint imposed on the nickel phase by the zirconia network. Measurements of damage in one pure nickel sample were also performed. The area fraction of voids as a function of local strain was found to follow an exponential relationship. The Young’s modulus of each material was determined ultrasonically and found to be uniform as expected. Modeling of the tensile specimens indicated that materials above the zirconia percolation threshold work harden more rapidly than those below it. This is not accounted for in the model by Ravichandran.