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DC Field | Value | Language |
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dc.contributor.advisor | MacLean, D.B. | - |
dc.contributor.author | Barclay, Lawrence | - |
dc.date.accessioned | 2020-07-22T19:37:55Z | - |
dc.date.available | 2020-07-22T19:37:55Z | - |
dc.date.issued | 1957-09 | - |
dc.identifier.uri | http://hdl.handle.net/11375/25549 | - |
dc.description.abstract | Hydride reductions of a-cyanobromolycopodine and simple derivatives provided a number of derivatives of these compounds useful for oxidation and dehydrogenation studies. Dehydrogenation of a-des-tetrahydrolycrodine yielded a quinoline derivative. This result together with other evidence indicated that three of the four rings of lycopodine are six-membered. Two conjugated enols were isolated from oxidation experiments on a -cyanlyopodine. This indicated the presence of an active methylene group and from examination of these enols it appears unlikely that the carbonyl and nitrogen can be in the same ring. A benzal derivative was prepared from a-cyanolycopodine. This derivative was converted into a tertiary base which under-went a bond scission reaction with methyl sulfate. A selenium dioxide oxidation product of benzal-a -cyanolyco-podine gave some indication of the relationship of the carbonyl to the nitrogen in lycopodlne. | en_US |
dc.language.iso | en | en_US |
dc.subject | chemistry | en_US |
dc.subject | lycopodine | en_US |
dc.title | The Chemistry of Lycopodine | en_US |
dc.type | Thesis | en_US |
dc.contributor.department | Chemistry | en_US |
dc.description.degreetype | Thesis | en_US |
dc.description.degree | Doctor of Philosophy (PhD) | en_US |
Appears in Collections: | Digitized Open Access Dissertations and Theses |
Files in This Item:
File | Description | Size | Format | |
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Barclay_Lawrence_R_1957Sep_PhD.pdf | 4.58 MB | Adobe PDF | View/Open |
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