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http://hdl.handle.net/11375/23667| Title: | Studies on the Chemistry of Annotinine |
| Authors: | Adams, Kenneth A.H. |
| Advisor: | MacLean, David B. |
| Department: | Chemistry |
| Keywords: | chemistry;annotinine |
| Publication Date: | Sep-1958 |
| Abstract: | The amino acid C14H19O4N, obtained from annotinine by oxidative fission of ring A, has been converted to the o,N-diacetyl acyclic anhydride C18H22O6N, and the anhydride ring has been shown to be five-membered. Oxidation studies have been carried out on the N-methyl lactone C17H27O2N, obtained by fission of ring A, and the oxidation products isolated and characterized. Hofmann degradation studies on the N-methyl lactone have been carried out and the products isolated from this reaction are discussed in relation to the known structure of the alkaloid. |
| URI: | http://hdl.handle.net/11375/23667 |
| Appears in Collections: | Digitized Open Access Dissertations and Theses |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| adams_kenneth_ah_1958sep_masters.pdf | 25.65 MB | Adobe PDF | View/Open |
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