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http://hdl.handle.net/11375/20681
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DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Warkentin, J. | - |
dc.contributor.author | West, Paul Ronald | - |
dc.date.accessioned | 2016-10-14T12:41:36Z | - |
dc.date.available | 2016-10-14T12:41:36Z | - |
dc.date.issued | 1967-03 | - |
dc.identifier.uri | http://hdl.handle.net/11375/20681 | - |
dc.description.abstract | <p> The reaction of lead tetra-acetate with ketone carbohydrazones and 4-substituted semicarbazones gave a series of 2-(substituted imino)-△^3-1,3,4-oxadiazolines. Spectroscopic and chemical evidence is presented to establish the proposed structure, and the scope of the reaction is described. The thermolysis of the 5,5-diaryl-2-phenylimino-△^3-1,3,4-oxadiazolines was studied in chlorobenzene solution. The results of kinetic experiments (gas evolution and infra-red) are reported, and the mechanism of the decomposition is discussed. A survey of the literature pertaining to related lead tetra-acetate oxidations, and to decomposition of cyclic azo compounds is presented.</p> | en_US |
dc.language.iso | en_US | en_US |
dc.subject | oxidative, cyclization, ketone, carbohydrazones, semicarbazones, decomposition, reaction | en_US |
dc.title | The Oxidative Cyclization of Ketone Carbohydrazones and 4-Substituted Semicarbazones. Thermal Decomposition of 5,5-Diaryl-2-Phenylimino-△^3 -1,3,4-Oxadiazolines | en_US |
dc.type | Thesis | en_US |
dc.contributor.department | Chemistry | en_US |
dc.description.degreetype | Thesis | en_US |
dc.description.degree | Doctor of Philosophy (PhD) | en_US |
Appears in Collections: | Digitized Open Access Dissertations and Theses |
Files in This Item:
File | Description | Size | Format | |
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West_Paul_R._1967Mar_Ph.D..pdf | 6.5 MB | Adobe PDF | View/Open |
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