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http://hdl.handle.net/11375/20673
Title: | Photochemistry of Triphenylmethylcyclopentadiene |
Authors: | Weigl, Stefan |
Advisor: | Warkentin, J. |
Department: | Chemistry |
Keywords: | photochemistry, direct irradiation, thermolytic isomerization |
Publication Date: | Sep-1975 |
Abstract: | <p> The products and mechanism of the photolytic rearrangement of the equilibrium mixture of triphenylmethylcyclopentadienes have been studied. Direct irradiation of the equilibrium mixture of triphenylmethylcyclopentadienes yields 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene. Photolysis with a triplet sensitizer yields dimeric products in addition to 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene. Thermolytic isomerization of 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene is reported. The predominant isomer in the equilibrium mixture of triphenylmethylcyclopentadiene has been established as 2-triphenylmethylcyclopentadiene.</p> |
URI: | http://hdl.handle.net/11375/20673 |
Appears in Collections: | Digitized Open Access Dissertations and Theses |
Files in This Item:
File | Description | Size | Format | |
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Weigl_Stefan_1975Sept_Masters..pdf | 1.97 MB | Adobe PDF | View/Open |
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