Reactions of Sulfur and Sulfur Containing Species with Amines

Please use this identifier to cite or link to this item: http://hdl.handle.net/11375/20141

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DC Field	Value	Language
dc.contributor.advisor	Olsen, F.P.	-
dc.contributor.author	Sasaki, Yukihiko	-
dc.date.accessioned	2016-08-15T16:37:17Z	-
dc.date.available	2016-08-15T16:37:17Z	-
dc.date.issued	1970-05	-
dc.identifier.uri	http://hdl.handle.net/11375/20141	-
dc.description	Title: Reactions of Sulfur and Sulfur Containing Species with Amines, Author: Yukihiko Sasaki, Location: Thode	en_US
dc.description.abstract	<p>The reactions of S4N4 with various amines, particularly benzylamines, have been investigated. Benzylamines give arylimine polysulfides, Schiff's bases and ammonia as products. The stoichiometric equation has been established. The reaction is quite sensitive to structural changes and appears limited to ring substituded benzylamines.</p> <p>Details of the reactions of primary amines with sulfur, one of the "neglected fields of research", have been investigated. Intermediates have been isolated and characterized and a reaction scheme has been proposed for the sulfur-benzylamine system. In this scheme benzylamine polysulfides and benzylidenimine polysulfides occur as cyclic intermediates. The final products are N-benzylidene benzylamine, ammonia and benzylammonia polysulfides.</p>	en_US
dc.language.iso	en	en_US
dc.title	Reactions of Sulfur and Sulfur Containing Species with Amines	en_US
dc.type	Thesis	en_US
dc.contributor.department	Chemistry	en_US
dc.description.degreetype	Thesis	en_US
dc.description.degree	Doctor of Philosophy (PhD)	en_US
Appears in Collections:	Open Access Dissertations and Theses

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