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http://hdl.handle.net/11375/19993| Title: | An Investigation of the Crystal Structure of dichloro-μ-tetra(n-butyrato)dirhenium(III) |
| Authors: | Restivo, Roderic J. |
| Advisor: | Lock, C.J.L. |
| Department: | Chemistry |
| Publication Date: | Sep-1967 |
| Abstract: | <p>Dichloro-μ-tetra(n-butyrato)dirhenium(III) was examined by x-rays and found to consist of a centrosymmetric dimeric unit in an eclipsed rotomeric configuration with a short rhenium-rhenium bond length of 2.20(2)Å. A long rhenium-chlorine bond 2.53(1)Å is present in the molecular unit.</p> <p>The bonding in Re2(O2C.C3H7-N)4CL2 is discussed with reference to similar carboxylate dimer structures.</p> <p>A preliminary report on the structure of Re2(O4C.C3H7-N)2 is also presented.</p> |
| Description: | Title: An Investigation of the Crystal Structure of dichloro-μ-tetra(n-butyrato)dirhenium(III), Author: Roderic J. Restivo, Location: Thode |
| URI: | http://hdl.handle.net/11375/19993 |
| Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Restivo_Roderic_J_1967_09_master.pdf | Title: An Investigation of the Crystal Structure of dichloro-μ-tetra(n-butyrato)dirhenium(III), Author: Roderic J. Restivo, Location: Thode | 17.19 MB | Adobe PDF | View/Open |
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