NMR Studies of Some Inorganic Fluorides

Please use this identifier to cite or link to this item: http://hdl.handle.net/11375/19943

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DC Field	Value	Language
dc.contributor.advisor	Gillespie, R. J.	-
dc.contributor.author	Quail, John	-
dc.date.accessioned	2016-07-26T16:38:00Z	-
dc.date.available	2016-07-26T16:38:00Z	-
dc.date.issued	1963-08	-
dc.identifier.uri	http://hdl.handle.net/11375/19943	-
dc.description.abstract	The F19 NMR spectrum of SF4 at - 101° C has been assigned as an A2B2 type spectrum, rather than A2X2 as previously reported. Sulphur and boron isotope effects on F19 NMR spectra have been observed for the first time and a new silicon isotope effect has been measured. An expression has been derived for the shape of the spectrum of a nucleus of spin I = 1/2 spin-spin coupled to a nucleus of spin I = 3/2 which is undergoing quadrupole relaxation. The derived expression is used to interpret the F19 spectra of BF3 and Cl03F over a wide temperature range. A new compound, IOF5, has been prepared, and identified by means of its F19 NMR spectrum.	en_US
dc.language.iso	en	en_US
dc.subject	NMR Studies	en_US
dc.subject	Inorganic Fluorides	en_US
dc.subject	isotope	en_US
dc.subject	chemistry	en_US
dc.title	NMR Studies of Some Inorganic Fluorides	en_US
dc.contributor.department	Chemistry	en_US
dc.description.degreetype	Thesis	en_US
dc.description.degree	Doctor of Philosophy (PhD)	en_US
Appears in Collections:	Open Access Dissertations and Theses

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