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http://hdl.handle.net/11375/19623
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DC Field | Value | Language |
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dc.contributor.advisor | Corsini, A. | - |
dc.contributor.author | Maludzinski, Miron J. | - |
dc.date.accessioned | 2016-06-22T19:30:43Z | - |
dc.date.available | 2016-06-22T19:30:43Z | - |
dc.date.issued | 1975-08 | - |
dc.identifier.uri | http://hdl.handle.net/11375/19623 | - |
dc.description.abstract | <p> New complexes formed between U(VI), Th(IV) and Sc(III) and tropolone have been prepared. These include the solvates UO2T2⋅X and ThT4⋅X (T = the tropolone anion; X =H2O and CH3OH), and the unsolvated chelate Sc3⋅. Some U(VI), Th(IV) and Sc(III) tropolonates reported in the literature have been re-examined and found to be incorrectly formulated.</p> <p> The adduct chelates UO2T2⋅HT, ScT3⋅HT and the previously unreported ThT4⋅HT have been prepared. Evidence has been presented for hydrogen-bonding in the additional monodentate tropolone ligand.</p> <p> The thermal conversion of the above solvates and adducts to yield UO2T2, ThT4 and ScT3 has been described.</p> <p> The ability of tropolone and other bidentate ligands to displace the water molecule in UO2T2⋅H2O and ThT4⋅H2O, and the addition of such ligands to ScT3, has been studied.</p> | en_US |
dc.language.iso | en_US | en_US |
dc.subject | uranium, thorium, scandium, complexes, tropolone, solvates, ligand, molecule | en_US |
dc.title | Uranium(VI), Thorium(IV) and Scandium(III) Complexes of Tropolone | en_US |
dc.type | Thesis | en_US |
dc.contributor.department | Chemistry | en_US |
dc.description.degreetype | Thesis | en_US |
dc.description.degree | Master of Science (MSc) | en_US |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
File | Description | Size | Format | |
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Maludzinski_Miron_J._1975Aug_Masters..pdf | 2.45 MB | Adobe PDF | View/Open |
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