Please use this identifier to cite or link to this item:
http://hdl.handle.net/11375/18491| Title: | The Electronic Absorption Spectrum of Thioformaldehyde (CH₂S) |
| Authors: | Judge, Richard Henry |
| Advisor: | King, G. W. |
| Department: | Chemistry |
| Keywords: | chemistry;electronic absorption spectrum;thioformaldehyde |
| Publication Date: | May-1977 |
| Abstract: | The ¹A₂ ← ¹A₁ (π* ← n) electronic absorption spectrum of thioformaldehyde vapour has been investigated. The six excited state fundamental frequencies for both CH₂S and CD₂S are determined from the vibrational analysis. The three rotation constants and three symmetric top distortion constants for the 0⁰₀, 4¹₀ and 3¹₀4³₀ bands of CH₂S and the 0⁰₀, 4¹₀ and 5¹₀ bands of CD2S are determined from a least squares rotational analysis of these bands. The rotational constants of the 0⁰₀ and 4¹₀ bands of CH₂S and CD₂S are used to determine the structure of the molecule in the excited state. |
| URI: | http://hdl.handle.net/11375/18491 |
| Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Judge_Richard_H_1977May_PhD.pdf | 72.53 MB | Adobe PDF | View/Open |
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