X-Ray Crystal Structure Investigation of [Re(C5H5N)4 O2]Cl.2H20

Please use this identifier to cite or link to this item: http://hdl.handle.net/11375/18106

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DC Field	Value	Language
dc.contributor.advisor	Lock, C. J. L.	-
dc.contributor.author	Krishnamachari, Narasimhan	-
dc.date.accessioned	2015-09-24T15:40:58Z	-
dc.date.available	2015-09-24T15:40:58Z	-
dc.date.issued	1968-05	-
dc.identifier.uri	http://hdl.handle.net/11375/18106	-
dc.description.abstract	<p> The crystal structure of dioxotetrapyridine-rhenium(V) chloride dihydrate has been determined by single crystal x-ray diffraction methods. The structure has been found to belong to the trans-dioxo- group of compounds. The Re=O bond in the structure has been shown to have a bond-order of about 2, with the average Re=O bond length of 1.76(J) A. The probable structures of the monohydrate and anhydrous dioxotetrapyridine-rhenium(V) chloride have been discussed on the basis of the observed pseudo-symmetric structure for the dihydrate with a non-centrosymmetric space group. The nature and strength of the hydrogen bonds in the structure have also been discussed.</p>	en_US
dc.language.iso	en_US	en_US
dc.subject	crystal, structure, x-ray, diffraction, bonds	en_US
dc.title	X-Ray Crystal Structure Investigation of [Re(C5H5N)4 O2]Cl.2H20	en_US
dc.type	Thesis	en_US
dc.contributor.department	Chemistry	en_US
dc.description.degreetype	Thesis	en_US
dc.description.degree	Master of Science (MSc)	en_US
Appears in Collections:	Open Access Dissertations and Theses

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