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http://hdl.handle.net/11375/18106| Title: | X-Ray Crystal Structure Investigation of [Re(C5H5N)4 O2]Cl.2H20 |
| Authors: | Krishnamachari, Narasimhan |
| Advisor: | Lock, C. J. L. |
| Department: | Chemistry |
| Keywords: | crystal, structure, x-ray, diffraction, bonds |
| Publication Date: | May-1968 |
| Abstract: | <p> The crystal structure of dioxotetrapyridine-rhenium(V) chloride dihydrate has been determined by single crystal x-ray diffraction methods. The structure has been found to belong to the trans-dioxo- group of compounds. The Re=O bond in the structure has been shown to have a bond-order of about 2, with the average Re=O bond length of 1.76(J) A. The probable structures of the monohydrate and anhydrous dioxotetrapyridine-rhenium(V) chloride have been discussed on the basis of the observed pseudo-symmetric structure for the dihydrate with a non-centrosymmetric space group. The nature and strength of the hydrogen bonds in the structure have also been discussed.</p> |
| URI: | http://hdl.handle.net/11375/18106 |
| Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Krishnamachari_Narasimhan_May1968_Masters..pdf | 2.06 MB | Adobe PDF | View/Open |
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