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http://hdl.handle.net/11375/17780
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DC Field | Value | Language |
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dc.contributor.advisor | Lock, C. J. L. | - |
dc.contributor.author | Forster, William L. | - |
dc.date.accessioned | 2015-07-23T15:06:49Z | - |
dc.date.available | 2015-07-23T15:06:49Z | - |
dc.date.issued | 1972-09 | - |
dc.identifier.uri | http://hdl.handle.net/11375/17780 | - |
dc.description.abstract | Re(hfac)₃ has been found to crystallize in a hexagonal unit cell but the detailed structure has not been completed because of disordering problems along the c axis. The two-dimensional structure of Re(hfac)₃ reveals C₃ symmetry and no distortion of the octahedron composed of the six Re-O bonds. Re(acac)₃ has been found to belong to the α-type isomorphous set designated by Astbury. From x-ray powder photographs, the structure of Re(acac)₃ has been demonstrated to have the same gross structural features as Mn(acac)₃ but is not necessarily isostructural. Arguments are presented to show that β-V(acac)₃ is representative of the β-modification and that the β-type isomorphous set crystallizes in a monoclinic unit cell with a β-angle of 90º. Rotational transitions between the three isomorphous sets have been examined and found to be energetically unfavourable. | en_US |
dc.language.iso | en | en_US |
dc.subject | chemistry | en_US |
dc.subject | x-ray structure | en_US |
dc.subject | Re(hfac)₃, Re(acac)₃, and Re(acac)₃ReO₄ | en_US |
dc.title | X-ray Crystal Structure Investigation of Re(hfac)₃, Re(acac)₃, and Re(acac)₃ReO₄. | en_US |
dc.contributor.department | Chemistry | en_US |
dc.description.degreetype | Thesis | en_US |
dc.description.degree | Master of Science (MSc) | en_US |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
File | Description | Size | Format | |
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Forester_William_L_1972Sept_MSc.pdf | 21.06 MB | Adobe PDF | View/Open |
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