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Please use this identifier to cite or link to this item: http://hdl.handle.net/11375/17538
Title: Rhenium β-Ketoenolate Complexes
Authors: Courrier, William Donald
Advisor: Lock, C.J.L.
Department: Chemistry
Keywords: reaction, rhenium, β-ketoenols, complexes
Publication Date: May-1971
Abstract: <p> The products of the reaction between oxomethoxodichlorobistriphenylphosphinerhenium(V) and acetylacetone are determined, characterized and correlated in terms of a reaction scheme. A series of rhenium(III) compounds, characteristic of reactions analogous to the one mentioned above, with other β-ketoenols is prepared and characterized. The syntheses and properties of tris-1,1,1-5,5,5-hexafluoropentane-2,4-dionatorhenium(III) and trispentane-2,4-dionatorhenium(III) are described. A new nitrido-rhenium complex, nitridochloro-1,1,1-5,5,5-hexafluoropentane-2,4-dionatobistriphenylphosphinerhenium(V) complex is prepared and characterized. A synthetic route to pyridine-acetylacetonate complexes of rhenium is described. </p>
URI: http://hdl.handle.net/11375/17538
Appears in Collections:Open Access Dissertations and Theses

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