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http://hdl.handle.net/11375/17507
Title: | 2-Substituted 8-Quinolinols as Terdentate Chelating Agents |
Authors: | Cassidy, Richard M. |
Advisor: | Corsini, A. |
Department: | Chemistry |
Keywords: | chemistry;2-substituted 8-quinolinol;chelating agent;terdentate, ligand;acid-base, tiration |
Publication Date: | Sep-1971 |
Abstract: | A series of 2-substituted 8-hydroxyquinolines have been prepared and their reactions with a number of metal ions studied. Acid-dissociation constants and metal-chelate formation constants have been determined. 2-(2'-Hydroxyphenyl), 2-(2'-pyridyl) and 2-hydrazino-8-hydroxyquinoline function as terdentate ligands. The latter two ligands form a number of protonated complexes some of which are unusually stable. This stability is likely due to hydrogen bonding. |
URI: | http://hdl.handle.net/11375/17507 |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
File | Description | Size | Format | |
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Cassidy_Richard_M_1971Sept_PhD.pdf | 6.03 MB | Adobe PDF | View/Open |
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