A Conductometric and Spectroscopic Investigation of Some Solutes in Anhydrous HF

Brownstein, Seth Morley

Please use this identifier to cite or link to this item: http://hdl.handle.net/11375/16399

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DC Field	Value	Language
dc.contributor.advisor	Gillespie, R.J.	-
dc.contributor.author	Brownstein, Seth Morley	-
dc.date.accessioned	2014-11-18T15:58:03Z	-
dc.date.available	2014-11-18T15:58:03Z	-
dc.date.issued	1970-02	-
dc.identifier.uri	http://hdl.handle.net/11375/16399	-
dc.description.abstract	<p> Conductivity measurements on liquid hydrogen fluoride solutions of some simple bases and fluoroanion salts were carried out, and a set of equivalent ionic conductivities have been determined. The conductivities of electrolytes in hydrogen fluoride have been compared to those of analogous electrolytes in water and strong acid solvents. A method for the investigation of more complex electrolytes was developed.</p> <p> The mode of ionization of adducts of sulfur tetrafluoride, thionyl tetrafluoride and selenium tetrafluoride with fluoride acceptors in hydrogen fluoride has been investigated by conductivity and nmr spectroscopy. The structures of the solid adducts have also been investigated by Raman spectroscopy. The structure and stability of other sulfur-oxide-fluoride adducts have been investigated and found to differ from adducts of thionyl tetrafluoride. </p>	en_US
dc.language.iso	en	en_US
dc.subject	conductivity	en_US
dc.subject	hydrogen fluoride	en_US
dc.subject	ionization	en_US
dc.subject	electrolytes	en_US
dc.title	A Conductometric and Spectroscopic Investigation of Some Solutes in Anhydrous HF	en_US
dc.type	Thesis	en_US
dc.contributor.department	Chemistry	en_US
dc.description.degreetype	Thesis	en_US
dc.description.degree	Doctor of Philosophy (PhD)	en_US
Appears in Collections:	Open Access Dissertations and Theses

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