Please use this identifier to cite or link to this item:
http://hdl.handle.net/11375/16376
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Brown, I.D. | - |
dc.contributor.author | Brandon, James Kenneth | - |
dc.date.accessioned | 2014-11-14T18:49:27Z | - |
dc.date.available | 2014-11-14T18:49:27Z | - |
dc.date.issued | 1967-10 | - |
dc.identifier.uri | http://hdl.handle.net/11375/16376 | - |
dc.description.abstract | X-ray diffraction experiments have been used to determine the structure of cesium methylsulfonate (CsCH₃SO₃), lithium hydrazinium sulfate (LiN₂H₅SO₄), above 160ºC and triclinic potassium dichromate (K₂Cr₂O₇). The solved CsCH₃SO₃ structure is compared with BaSO₄ and the CsCH₃SO₃⁻¹ ion stereochemistry is dicussed in terms of a current theory of bonding for such groups. The previously known structure of room temperature ferroelectric LiN₂H₅SO₄ has recieved additional refinement and a comparison is made with the structure determined above 160ºC. The symmetry and structure found for K₂Cr₂O₇ are compared with similar compounds and predictions are given for the yet unsolved structures of other K₂Cr₂O₇ phases. The first accurate data for the Cr₂O₇⁻² ion stereochemistry is presented. This ion is compared to similar ones, and the possibility of extending a bonding theory to such ions involving chromium is discussed. | en_US |
dc.language.iso | en | en_US |
dc.subject | X ray diffraction | en_US |
dc.subject | cesium methylsulfonate | en_US |
dc.subject | lithium hydrazinium sulfate | en_US |
dc.subject | triclinic potassium dichromate | en_US |
dc.subject | structures | en_US |
dc.title | The Crystal Structures of CsCH₃SO₃, LiN₂H₅SO₄, and K₂Cr₂O₇ | en_US |
dc.type | Thesis | en_US |
dc.contributor.department | Physics | en_US |
dc.description.degreetype | Thesis | en_US |
dc.description.degree | Doctor of Philosophy (PhD) | en_US |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Brandon James K .pdf | Main Thesis | 5.72 MB | Adobe PDF | View/Open |
Items in MacSphere are protected by copyright, with all rights reserved, unless otherwise indicated.