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http://hdl.handle.net/11375/10885
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DC Field | Value | Language |
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dc.contributor.advisor | Childs, R. F. | en_US |
dc.contributor.author | Hine, Ernest Kenneth | en_US |
dc.date.accessioned | 2014-06-18T16:52:51Z | - |
dc.date.available | 2014-06-18T16:52:51Z | - |
dc.date.created | 2009-08-05 | en_US |
dc.date.issued | 1973-08 | en_US |
dc.identifier.other | opendissertations/59 | en_US |
dc.identifier.other | 1556 | en_US |
dc.identifier.other | 924583 | en_US |
dc.identifier.uri | http://hdl.handle.net/11375/10885 | - |
dc.description.abstract | <p>This thesis has resolved some rather fundamental and rudimentary questions concerning the photochemistry of cyclohepta-2,4-dienones.</p> <p>A new approach has been taken to assess the role of (π,π*) excited states in the photoisomerizations of 2,6,6-trimethylcyclohepta-2,4-dienone, eucarvone. It involved an investigation of the low temperature photorearrangements of protonated eucarvone in fluorosulphuric acid. The results, in additions to those obtained from a re-examination of neutral eucarvone photochemistry, have demonstrated that both (π,π*) and (π,π*) states are involved in the formation of primary photoproducts. A scheme has been formulated which relates these products to these excited states.</p> <p>An investigation of the photoisomerizations of cyclohepta-2,4-dienone and 2-methylcyclohepta-2,4-dienone has revealed that substituents have a profound influence upon the mode of reaction of the (π,π*) states of this dienone system. Whereas eucarvone was found to produce 3,7,7-trimethylbicyclo[4.1.0]hept-2-en-4-one from this state, the less substituted systems yielded only bicyclo [2.2.1]hept-2-en-7-ones. This substituent effect has been interpreted mechanistically in terms of an intermediate in the eucarvone reaction in which positive charge is developed upon the carbon bearing the two methyl groups.</p> <p>A novel synthesis of cyclohepta-2,4-dienone has been developed which involved as the key step the thermal isomerization of protonated cyclohepta-3,5-dienone.</p> | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Chemistry | en_US |
dc.title | Photoisomerizations of Cyclohepta-2,4-dienones | en_US |
dc.type | thesis | en_US |
dc.contributor.department | Chemistry | en_US |
dc.description.degree | Doctor of Philosophy (PhD) | en_US |
Appears in Collections: | Open Access Dissertations and Theses |
Files in This Item:
File | Size | Format | |
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fulltext.pdf | 4.64 MB | Adobe PDF | View/Open |
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